Expanding the coordination chemistry of donor-stabilized group-14 metalenes.

نویسندگان

  • Javier A Cabeza
  • Pablo García-Álvarez
  • Diego Polo
چکیده

The transformation of an amidinate germylene, equipped with just one accessible lone pair of electrons on the Ge atom, into a bidentate 4-electron donor κ(2)Ge,N-ligand, has been achieved for the first time, opening new doors to the non-carbene-like coordination chemistry of heavier carbene analogues.

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عنوان ژورنال:
  • Dalton transactions

دوره 42 5  شماره 

صفحات  -

تاریخ انتشار 2013